Communication: Direct tests of single-parameter aging.

نویسندگان

  • Tina Hecksher
  • Niels Boye Olsen
  • Jeppe C Dyre
چکیده

This paper presents accurate data for the physical aging of organic glasses just below the glass transition probed by monitoring the following quantities after temperature up and down jumps: the shear-mechanical resonance frequency (∼360 kHz), the dielectric loss at 1 Hz, the real part of the dielectric constant at 10 kHz, and the loss-peak frequency of the dielectric beta process (∼10 kHz). The setup used allows for keeping temperature constant within 100 μK and for thermal equilibration within a few seconds after a temperature jump. The data conform to a new simplified version of the classical Tool-Narayanaswamy aging formalism, which makes it possible to calculate one relaxation curve directly from another without any fitting to analytical functions.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 142 24  شماره 

صفحات  -

تاریخ انتشار 2015